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排序方式: 共有2305条查询结果,搜索用时 15 毫秒
51.
52.
《Arabian Journal of Chemistry》2020,13(12):8848-8887
Phthalocyanine (Pc) complexes are an important class of dyes with numerous (e.g., biological, photophysical, and analytical) applications. Among the methods used to improve the properties of these complexes, one should mention the introduction of different substituents, variation of the central metal ion, ligand exchange, and conjugation to nanomaterials (e.g., carbon-based nanomaterials and metal nanoparticles (NPs)). This work briefly reviews Pc complex conjugation to Ag and Au NPs, highlights the different NP shapes, and discusses the diversity of conjugation approaches. Moreover, the use of UV–Vis spectroscopy, powder X-ray diffraction, X-ray photoelectron spectroscopy, transmission electron microscopy, atomic force microscopy, dynamic light scattering and Fourier transform infrared spectroscopy to characterize Pc-NP hybrids is summarized. The effect of conjugation on Pc photo-physicochemical properties (fluorescence, singlet oxygen generation, triplet state formation, and optical limiting behavior) is discussed, and future perspectives for the synthesis and applications of new hybrids are provided. 相似文献
53.
Helmut Ehrenberg Hermann Pauly Joachim Gröbner 《Journal of solid state chemistry》2004,177(1):227-230
The cubic face-centered structure of LiAl (, at ) transforms into a tetragonal body-centered structure (I41/amd, , at ). This first-order phase transition at about during heating is probably the reason for the so-called “ anomalies” in some physical properties like specific heat, electrical resistivity and nuclear-spin lattice relaxation. This transition seems to be correlated with the composition Li:Al of the alloy and the amount of Li vacancies. 相似文献
54.
Cellulase retention and sugar removal by membrane ultrafiltration during lignocellulosic biomass hydrolysis 总被引:1,自引:0,他引:1
Technologies suitable for the separation and reuse of cellulase enzymes during the enzymatic saccharification of pretreated
corn stover are investigated to examine the economic and technical viability of processes that promote cellulase reuse while
removing inhibitory reaction products such as glucose and cellobiose. The simplest and most suitable separation is a filter
with relatively large pores on the order of 20–25 mm that retains residual corn stover solids while passing reaction products
such as glucose and cellobiose to form a sugar stream for a variety of end uses. Such a simple separation is effective because
cellulase remains bound to the residual solids. Ultrafiltration using 50-kDa polyethersulfone membranes to recover cellulase
enzymes in solution was shown not to enhance further the saccharification rate or overall conversion. Instead, it appears
that the necessary cellulase enzymes, including β-glucosidase, are tightly bound to the substrate; when fresh corn stover
is contacted with highly washed residual solids, without the addition of fresh enzymes, glucose is generated at a high rate.
When filtration was applied multiple times, the concentration of inhibitory reaction products such as glucose and cellobiose
was reduced from 70 to 10 g/L. However, an enhanced saccharification performance was not observed, most likely because the
concentration of the inhibitory products remained too high. Further reduction in the product concentration was not investigated,
because it would make the reaction unnecessarily complex and result in a product stream that is much too dilute to be useful.
Finally, an economic analysis shows that reuse of cellulase can reduce glucose production costs, especially when the enzyme
price is high. The most economic performance is shown to occur when the cellulase enzyme is reused and a small amount of fresh
enzyme is added after each separation step to replace lost or deactivated enzyme. 相似文献
55.
高效液相色谱法测定糙米粉中的维生素 总被引:7,自引:1,他引:7
高效液相色谱法测定糙米粉中的维生素吴红京,唐根源,王勇(中国科学院福建物质结构研究所福州350002)(福建药品检验所福州350001)1前言众所周知,糙米粉有很高的营养价值,含有人体必需的多种维生素。用高效液相色谱法(HPLC)和薄层色谱法(TLC... 相似文献
56.
采用高能球磨法制备了纳米晶掺Y硬质合金粉末。用XRD,SEM和DTA等分析检测手段,研究了纳米晶掺Y硬质合金粉末的结构、形貌和相的变化。结果表明:高能球磨45h,可获得晶粒尺寸约为8nm的掺Y硬质合金粉末;微量Y的加入,有利于硬质合金粉末晶粒的细化;在25~45h范围内,随着高能球磨时间的延长,粉末晶粒尺寸减小,且掺Y硬质合金粉末的晶粒尺寸比未掺Y的硬质合金粉末晶粒尺寸要细一倍;高能球磨25h,粉末中Co的X射线衍射峰消失。高能球磨掺Y硬质合金粉末的DTA曲线在626℃出现了1个尖锐的放热峰。高能球磨掺Y硬质合金粉末固结之后,其合金晶粒细小,机械性能较好。 相似文献
57.
《Surface and interface analysis : SIA》2004,36(1):92-95
By using modern XPS systems it is possible to obtain spectra with well‐resolved spin orbit, multiplet and field splitting even with powder samples mounted using adhesive tape. Measurement of Cr2O3 powder with the latest generation of XPS spectrometers, which are able to analyse non‐conductive powders with ultimate energy resolution, revealed multiplet splitting features and satellite emission in the Cr 2p spectrum. Therefore, peak‐fit analysis of Cr 2p XPS spectra of Cr(III) compounds requires a more appropriate approach and common practice has to be reconsidered. One possible way to analyse this spectrum is proposed, based on the experimental and theoretical work of other authors. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
58.
P. Torline G. du Plessis N. Schnautz J. C. Thompson 《Journal of separation science》1979,2(10):613-616
A detailed method for the routine preparation of glass capillary columns is presented. The method consists of coating a glass tube with quartz powder prior to pulling the tube into a capillary. The inner surface of the capillary consists of an even distribution of quartz particles fused to the walls. This surface has been found readily deactivated by standard procedures and ideal for the preparation of thick-film glass capillary columns. The method has been thoroughly tested in two independent laboratories to ensure that the procedures described are reproducible. 相似文献
59.
Ludvík Beneš Vítězslav Zima 《Journal of inclusion phenomena and macrocyclic chemistry》1994,20(4):381-391
The course of intercalation of water into 1-VOPO4 has been studied by thermomechanical analysis and X-ray diffraction. Neither formation of vanadyl phosphate monohydrate nor staging were observed during the intercalation. The broadening and the shift of the positions of the lines in the diffractograms have been explained by the random stacking of intercalated and nonintercalated layers in the sample. 相似文献
60.
已证明小儿厌食症除与缺乏微量元素锌关系密切外,还与其他多种微量元素和宏量元素的缺乏或低下也有关。本院以自行研制的中药强壮灵冲剂治疗小儿厌食症疗效显著。其于浸膏粉经20余种微量元素测定表明含有锌、铁、钴、铜、镍、锰、铬、锗、锶、铝、钡、硒、硅、钛等多种人体必需且品种齐全,含量适度的微量元素。上述元素又恰是患儿体内所缺乏和低下的品种,无疑对患儿全面适度的补充大有裨益.中药强壮灵与西药硫酸锌临床对比研究表明,无论比发锌回升数值以及从厌食等全面疗效统计,中药组均明显优于西药组,并且发现疗效与药物的补锌量不成正相关。说明中药的调理脾胃功能及综合整体治疗作用是其突出优点,值得推广. 相似文献